demonstrations:making_chlorine_gas
Making Chlorine Gas
Materials: ★★☆ Available in most school laboratories or specialist stores
Difficulty: ★★☆ Can be done by science teachers
Safety: ★★★ Only to be attempted with adequate safety procedures and trained staff
Categories: Elements and Periodic Table, Gases
Alternative titles: Preparation of Chlorine from Permanganate
Summary
Chlorine gas, a pale greenish-yellow substance, can be produced by reacting potassium permanganate with concentrated hydrochloric acid.
Procedure
- Place a small quantity of potassium permanganate crystals into a flask.
- Add concentrated hydrochloric acid drop by drop onto the crystals.
- Collect the chlorine gas by upward displacement of air (chlorine is denser than air) inside a fume hood.
- Observe the characteristic pale green-yellow color of chlorine gas.
Links
Make Chlorine Gas (fixed) - NurdRage:
Preparation of chlorine - Hegelrast:
📄 How to Make Chlorine Gas - Science Notes: https://sciencenotes.org/make-chlorine-gas/
Variations
- Compare this method with chlorine production from the electrolysis of brine.
- Test chlorine’s bleaching properties using damp litmus paper (it is bleached and turns white).
Safety Precautions
- Chlorine gas is toxic — conduct only in a fume hood.
- Wear chemical splash goggles, gloves, and a lab coat.
- Concentrated hydrochloric acid is highly corrosive — handle with extreme care.
- Do not inhale chlorine; exposure may cause severe respiratory harm.
- Dispose of residues safely following institutional guidelines.
Questions to Consider
- What is the balanced chemical equation for this reaction? (6HCl + 2KMnO₄ → 3Cl₂ + 2MnO₂ + 4H₂O + 2K⁺)
- Why is chlorine collected by upward displacement of air? (It is denser than air.)
- What are some uses of chlorine gas? (Water disinfection, bleach production, PVC plastics.)
- Why is chlorine considered dangerous to work with? (It is toxic, corrosive, and can cause lung damage.)
- How does this reaction demonstrate both oxidation and reduction? (Mn is reduced from +7 to +4, Cl⁻ is oxidized to Cl₂.)