demonstrations:liquid_nitrogen_freezing_marshmallows
Liquid Nitrogen Freezing Marshmallows
Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★☆ Can be done by science teachers
Safety: ★★★ Only to be attempted with adequate safety procedures and trained staff
Categories: Food Science and Nutrition, Liquid Nitrogen
Alternative titles: Dragon’s Breath Marshmallows
Summary
Marshmallows frozen in liquid nitrogen become crisp and brittle. When eaten, the extreme cold condenses the water vapor in exhaled breath, creating a dramatic “dragon’s breath” fog effect.
Procedure
- Fill a large insulated bowl with liquid nitrogen.
- Place regular-size marshmallows into the bowl.
- Use a wooden spoon to push the marshmallows down and stir them so they freeze evenly.
- Once frozen, remove a marshmallow with tongs and serve to a volunteer.
- Instruct the volunteer to chew with their mouth slightly open and exhale gently.
- Observe the “dragon’s breath” fog effect as condensed vapor exits their mouth and nose.
Links
Liquid Nitrogen Marshmallows Experiment - Crus Center:
📄 Liquid Nitrogen Marshmallows - Harvard Natural Sciences Lecture Demonstrations: https://sciencedemonstrations.fas.harvard.edu/presentations/liquid-nitrogen-marshmallows
Variations
- Try different foods (cheese puffs, crackers) to see how they behave when frozen.
- Compare the texture of frozen versus room-temperature marshmallows.
- Use colored lighting to make the fog effect more dramatic during a demonstration.
Safety Precautions
- Safety glasses required for the demonstrator.
- Wear cryogenic gloves when handling liquid nitrogen.
- Use only wooden or plastic utensils (metal gets dangerously cold).
- Never serve marshmallows until liquid nitrogen has fully evaporated.
- Ensure volunteers understand to chew slowly — swallowing liquid nitrogen is extremely dangerous.
- Only serve in supervised, controlled demonstration settings.
Questions to Consider
- Why does frozen marshmallow create visible fog when exhaled?
- What role does water vapor in breath play in this effect?
- How does liquid nitrogen change the texture of marshmallows?
- Why is it safe to eat the marshmallows only after the nitrogen evaporates?
- How is this effect similar to seeing your breath on a cold morning?