demonstrations:led_color_change_in_liquid_nitrogen

LED Color Change in Liquid Nitrogen

Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★☆ Can be done by science teachers
Safety: ★★★ Only to be attempted with adequate safety procedures and trained staff

Categories: Liquid Nitrogen

Alternative titles: Cryogenic LED Demonstration

Summary

When an LED is submerged in liquid nitrogen, its emitted light shifts in color.

Procedure

  1. Connect an LED to a safe low-voltage battery circuit.
  2. Confirm the LED is lit at room temperature and note its color.
  3. Wearing cryogenic gloves and safety glasses, carefully immerse the lit LED into a container of liquid nitrogen.
  4. Observe the change in color (typically a shift toward higher-energy light, e.g., orange → yellow, yellow → green).
  5. Remove the LED from liquid nitrogen and watch it return to its original color as it warms.

Why Do Yellow LEDs Change Color in Liquid Nitrogen? - Baltic Lab:


📄 The Physics Well: https://the-physics-well.net/its-not-easy-explaining-green/

📄 Why LED light changes color when dips into liquid nitrogen? - Stack Exchange: https://physics.stackexchange.com/questions/611567/why-led-light-changes-color-when-dips-into-liquid-nitrogen

Variations

  • Try different colors of LEDs (red, green, blue) to see how the degree of color shift differs.
  • Compare inorganic semiconductor LEDs with organic LEDs (OLEDs), which may show opposite behavior due to molecular effects.
  • Use a spectrometer or diffraction grating to measure the wavelength shift more precisely.

Safety Precautions

  • Safety glasses required.
  • Wear cryogenic gloves when handling liquid nitrogen.
  • Ensure electrical leads are insulated and avoid short circuits in the presence of liquid nitrogen.
  • Use only in a well-ventilated area to prevent nitrogen gas buildup.
  • Never submerge batteries or power sources - only the LED and wires should contact the liquid nitrogen.

Questions to Consider

  • Why does lowering temperature increase the band gap in semiconductor LEDs?
  • How does a larger band gap lead to higher-energy (shorter wavelength) photons?
  • Why might organic LEDs (OLEDs) show a red-shift instead of a blue-shift when cooled?
  • What real-world technologies depend on the temperature sensitivity of semiconductors?
  • How could this experiment be used to introduce the concept of the quantum nature of light?