Ammonia Fountain
Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★★ Requires a more experienced teacher
Safety: ★★★ Only to be attempted with adequate safety procedures and trained staff
Categories: Acids and Bases, Gases, Water and Solubility, Pressure and Fluids
Alternative titles: [ * ]
Summary
Dry ammonia gas is collected in a sealed flask. When a small amount of water is injected, the ammonia rapidly dissolves, creating a partial vacuum that pulls water up into the flask. An indicator shows the resulting alkaline solution.
Procedure
- Generate ammonia gas by gently heating a mixture of ammonium chloride and calcium hydroxide in a test tube.
- Pass the ammonia through a drying tube to remove moisture.
- Collect the dry ammonia in a sealed, dry flask kept warm until use.
- Set up the flask inverted in a water trough with a jet tube connected.
- Add phenolphthalein indicator to the water in the trough.
- Inject a small amount of water into the flask using a syringe.
- Observe as the ammonia dissolves in the water, lowering pressure inside the flask.
- Watch the water rush into the flask, creating a “fountain” effect and turning pink from the alkaline solution.
Links
Ammonia Fountain - North Carolina School of Science and Mathematics:
The Ammonia Fountain - Super Cool Science - Explained - Jon Bergmann:
📄 Ammonia fountain - Dynamic Science: https://www.dynamicscience.com.au/tester/solutions1/chemistry/chemicaldemos/ammonia.html
Variations
- Use different indicators (e.g., universal indicator) to show color changes.
Safety Precautions
- Eye protection required.
- Perform the experiment in a fume cupboard due to toxic ammonia gas.
- Handle hot glassware and chemicals with care.
- Ensure the collection flask is completely dry before use, as moisture reduces effectiveness.
- Clamp apparatus securely to prevent tipping.
- Do not inhale ammonia gas; ensure good ventilation.
Questions to Consider
- Why does the water rush into the flask so quickly?
- How does the solubility of ammonia in water compare with other gases?
- What role does the indicator play in this experiment?
- What chemical species are present in the solution after ammonia dissolves?
- How would the demonstration change if the flask contained air instead of ammonia?