demonstrations:ammonia_fountain

Ammonia Fountain

Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★★ Requires a more experienced teacher
Safety: ★★★ Only to be attempted with adequate safety procedures and trained staff

Categories: Acids and Bases, Gases, Water and Solubility, Pressure and Fluids

Alternative titles: [ * ]

Summary

Dry ammonia gas is collected in a sealed flask. When a small amount of water is injected, the ammonia rapidly dissolves, creating a partial vacuum that pulls water up into the flask. An indicator shows the resulting alkaline solution.

Procedure

  1. Generate ammonia gas by gently heating a mixture of ammonium chloride and calcium hydroxide in a test tube.
  2. Pass the ammonia through a drying tube to remove moisture.
  3. Collect the dry ammonia in a sealed, dry flask kept warm until use.
  4. Set up the flask inverted in a water trough with a jet tube connected.
  5. Add phenolphthalein indicator to the water in the trough.
  6. Inject a small amount of water into the flask using a syringe.
  7. Observe as the ammonia dissolves in the water, lowering pressure inside the flask.
  8. Watch the water rush into the flask, creating a “fountain” effect and turning pink from the alkaline solution.

Ammonia Fountain - North Carolina School of Science and Mathematics:


The Ammonia Fountain - Super Cool Science - Explained - Jon Bergmann:


📄 Ammonia fountain - Dynamic Science: https://www.dynamicscience.com.au/tester/solutions1/chemistry/chemicaldemos/ammonia.html

Variations

  • Use different indicators (e.g., universal indicator) to show color changes.

Safety Precautions

  • Eye protection required.
  • Perform the experiment in a fume cupboard due to toxic ammonia gas.
  • Handle hot glassware and chemicals with care.
  • Ensure the collection flask is completely dry before use, as moisture reduces effectiveness.
  • Clamp apparatus securely to prevent tipping.
  • Do not inhale ammonia gas; ensure good ventilation.

Questions to Consider

  • Why does the water rush into the flask so quickly?
  • How does the solubility of ammonia in water compare with other gases?
  • What role does the indicator play in this experiment?
  • What chemical species are present in the solution after ammonia dissolves?
  • How would the demonstration change if the flask contained air instead of ammonia?