Test for Hard Water
Materials: ★☆☆ Easy to get from supermarket or hardware store
Difficulty: ★☆☆ Can be easily done by most teenagers
Safety: ★☆☆ Minimal safety procedures required
Categories: Water and Solubility
Alternative titles:
Summary
Use liquid soap and vigorous shaking in a clear, stoppered vessel to compare suds height and cloudiness in water samples. Soft water makes abundant stable foam; hard water forms little foam and turns cloudy as calcium/magnesium ions react with soap.
Procedure
Add 100 mL of a water sample to a clean test tube; mark the water line (for reference).
Add 1.0 mL of a liquid soap solution (≈20 drops if no pipette); stopper.
Shake vigorously for 10 seconds; set down for 10 seconds; observe foam height and clarity of the liquid below.
Repeat the test with DI water (soft-water control) and additional sources (e.g., other taps) under identical volumes and timing.
Interpret: abundant, long-lasting foam with clear water indicates soft water; scant foam with cloudy/scummy water indicates hardness proportional to the soap volume required.
Links
Variations
Prepare known mixtures of DI water and tap water (e.g., 25%, 50%, 75%) to create a semi-quantitative calibration of “soap volume to persistent foam.”
Compare soap vs a synthetic detergent to illustrate why detergents lather even in hard water.
Collect samples from hot vs cold taps and rank their relative hardness.
Safety Precautions
Questions to Consider
Why must soap be used, not detergent? (Detergents lather in hard water; true soap reacts with Ca²⁺/Mg²⁺ to form insoluble scum, suppressing foam.)
Why does hard water turn cloudy on shaking? (Formation of insoluble calcium/magnesium soaps.)
How does the “soap volume to persistent foam” relate to hardness? (More soap required implies higher concentrations of Ca²⁺/Mg²⁺.)
Why run a DI water control? (To show the maximum foam response and check your shaking/timing method.)
How would boiling affect your results? (It can remove temporary hardness by precipitating carbonates, increasing foam in the boiled sample.)