======Triple Point of Water====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Coexistence of Solid, Liquid, and Gas in Water ====Summary==== {{$demo.summary}} ====Procedure==== - Cool water with ice and pour into a watch glass until half full. - Place the watch glass on an insulating stand inside a bell jar. - Seal the jar onto the rubber mat base. - Connect the bell jar to a vacuum pump via a drying trap filled with calcium sulfate (Drierite). - Turn on the vacuum pump and reduce the pressure. At about 28 mm Hg, water begins to boil. - Continue evacuation for several minutes. Ice will form on the surface while liquid water boils below it. - Discuss the observed coexistence of solid, liquid, and gas. ====Links==== Triple Point of Water - UCSC Physics: {{youtube>Juz9pVVsmQQ?}}\\ 📄 Triple Point of Water - UCSC Physics Demonstration Room: [[https://ucscphysicsdemo.sites.ucsc.edu/physics-5b6b-demos/triple-point-of-water/]]\\ ====Variations==== * Use a video camera for projection in large lecture halls. * Repeat with other substances (e.g., carbon dioxide using dry ice) to compare triple points. * Plot observed behavior on a phase diagram to connect the demonstration with theoretical models. ====Safety Precautions==== * Operate the vacuum pump carefully and ensure connections are secure to prevent implosion. * Use a water vapor trap to protect the vacuum pump from excess water vapor. * Handle glassware with care to avoid breakage under reduced pressure. ====Questions to Consider==== * What is the triple point of water? (The unique temperature and pressure at which water’s solid, liquid, and gas phases coexist—0.1 °C and 0.006 atm.) * Why does water boil under reduced pressure even when it is cold? (Lowering pressure reduces the boiling point of water, allowing it to vaporize at near 0 °C.) * Why does ice form at the same time water is boiling? (Evaporation removes energy, cooling the liquid until it freezes, while pressure keeps boiling ongoing.) * Why is the triple point important in science? (It provides a fundamental reference point for defining temperature scales and understanding phase behavior.)