======Sodium in Water====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** ====Summary==== {{$demo.summary}} ====Procedure==== Note: this uses a tiny piece of sodium that shouldn't explode. See [[sodium_in_water_explosion|here]] for the explosive version. - Place a beaker in a secondary tray and fill it about halfway with water. - Add a few drops of a pH indicator such as phenolphthalein to the water. - Using dry tongs, cut and remove a pea-sized piece of sodium from oil storage and quickly blot surface oil with a dry tissue. - Stand back and gently place the sodium piece onto the water surface. - Observe fizzing, the metal skittering on the surface, hydrogen evolution, possible ignition, and the indicator trail turning pink as sodium hydroxide forms. ====Links==== Reaction of Sodium and Water - North Carolina School of Science and Mathematics: {{youtube>dmcfsEEogxs?}}\\ 📄 Sodium in Water Chemistry Demonstration - Science Notes: [[https://sciencenotes.org/sodium-in-water-chemistry-demonstration/]]\\ ====Variations==== * Use different indicators (phenolphthalein, universal indicator) to visualize the pH increase. * Demonstrate group trends qualitatively by discussing lithium (milder) and potassium (more vigorous) behavior rather than performing them, or show vetted video clips for comparison. ====Safety Precautions==== * Teacher demonstration only; do not scale up the sample size beyond pea-sized. * Wear splash goggles, face shield, lab coat, and appropriate gloves; keep students behind a safety shield and at a safe distance. * Store sodium under mineral oil or kerosene; handle with dry tools and dry hands away from water sources. * Use only a borosilicate beaker placed in a larger tray for containment; keep flammables away. * Expect hydrogen gas; avoid open flames and ignition sources. * Keep a Class D option such as dry sand available; do not use water or CO₂ extinguishers on alkali metal fires. * After the reaction, treat the solution as sodium hydroxide; optionally neutralize with dilute acid (e.g., vinegar) before disposal per local rules. ====Questions to Consider==== * Why does sodium float on water? (Its density is about 0.97 g/cm³, lower than water.) * What products form in the reaction, and how does the indicator show this? (Sodium hydroxide and hydrogen; the base raises pH so phenolphthalein turns pink.) * Why can flames appear even without an external spark? (The exothermic reaction can heat and ignite the hydrogen in air.) * Why is sodium metal far more reactive than sodium chloride in water? (Na metal readily loses an electron; in NaCl the sodium already exists as Na⁺ and simply dissolves.) * How does reactivity change down Group 1, and why? (It increases from Li to Cs due to lower ionization energy and weaker attraction to the outer electron.)