======Nylon Rope Trick====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Interfacial Polymerization of Nylon ====Summary==== {{$demo.summary}} ====Procedure==== - Pour 25 mL of 5% aqueous 1,6-diaminohexane into a crystallizing dish. - Carefully layer 25 mL of 5% adipoyl chloride in cyclohexane on top, ensuring the two solutions do not mix. - At the interface, a thin film of nylon will form. - Using forceps, grasp the nylon film and gently pull upward in a steady motion. - Wind the continuous nylon thread around a test tube or roller to collect the polymer. ====Links==== Nylon Rope Trick - Wisconsin Mrsec (Education): {{youtube>jFM-iMyvg4c?}}\\ Carolina Science - Nylon Synthesis Chemistry Demo: {{youtube>NQpTQFGKRN8?}}\\ 📄 Nylon Rope Trick - University of Washington: [[https://chem.washington.edu/lecture-demos/nylon-rope-trick]]\\ ====Variations==== * Compare interfacial polymerization with bulk polymerization methods. ====Safety Precautions==== * Adipoyl chloride is corrosive and a lachrymator - avoid inhalation and skin contact. * Cyclohexane is flammable and malodorous—keep away from flames and work in a well-ventilated area. * 1,6-diaminohexane is corrosive - wear gloves, goggles, and a lab coat. * Use an absorptive pad to contain spills and dispose of chemicals properly. ====Questions to Consider==== * Why does nylon form at the interface between the two layers? (The monomers react only at the boundary where they come into contact, producing a thin polymer film.) * What type of reaction produces nylon in this demonstration? (Condensation polymerization, forming amide bonds.) * Why is this demonstration called the “Nylon Rope Trick”? (Because a long strand of nylon can be pulled continuously like a rope.) * What are some real-world applications of nylon? (Clothing, ropes, fishing line, engineering plastics.)