======Leach Mining====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Acid Leaching of Copper Ore ====Summary==== {{$demo.summary}} ====Procedure==== - Place a small amount of copper carbonate (the model mineral) into a large beaker. - Fill the beaker with fine crushed rock to a few centimeters below the rim. - Prepare an “injection well” by inserting a pencil into a 10 cm plastic tube, drilling a hole down into the rock, then removing the pencil. - Set up a filter funnel in a retort stand above the injection well, and connect the funnel outlet to the plastic tube. Ensure the lower end of the tube is about 0.5 cm from the beaker bottom. - Slowly pour about 100 mL of 0.1M sulfuric acid into the funnel. Allow it to percolate through the crushed rock for about 2 minutes. - Prepare a “recovery well” by drilling another hole using the second plastic tube and pencil, about 0.5 cm from the beaker bottom on the opposite side. Remove the pencil. - Attach a syringe to a thin plastic tube and insert it into the recovery well. - Pull the syringe plunger gently to extract the leachate, and collect liquid in a test tube. - Add an iron nail to the test tube of recovered liquid and observe changes over several minutes. ====Links==== *None available ====Variations==== * Try using different acid concentrations to compare extraction rates. * Substitute copper carbonate with another carbonate mineral such as malachite or azurite. * Use different metals (e.g., zinc, iron) for the recovery step to compare displacement reactions. * Repeat the process using vinegar as a safer weak acid alternative for younger students. ====Safety Precautions==== * Wear safety glasses and gloves at all times. * Sulfuric acid is corrosive, handle with care and rinse spills immediately with water. * Do not inhale fumes or touch acid-soaked materials. * Dispose of copper-containing waste as directed by your instructor or local regulations. ====Questions to Consider==== * What part of the setup represents the ore body, leach solution, injection well, and recovery well? * How does this model demonstrate the process of leach mining in real-world operations? * What chemical reaction occurs when sulfuric acid reacts with copper carbonate? (CuCO₃ + H₂SO₄ → CuSO₄ + H₂O + CO₂) * What happened when the iron nail was placed in the blue copper sulfate solution? (Copper metal was displaced and deposited on the nail.) * How could the copper recovered from the leach solution be purified in an actual mining operation?