======Hydrogen and Oxygen Exploding Bubbles====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Electrolysis Bubbles Explosion ====Summary==== {{$demo.summary}} ====Procedure==== - Set up a side-arm boiling tube with lead foil electrodes, a bung, and a delivery tube connected to a beaker of soapy water. - Fill the tube with sulfuric acid solution until just below the side-arm. Seal with the bung. - Place the delivery tube near (but not yet in) the soapy water. - Connect electrodes to a 12 V DC power supply with an ammeter, and switch on (1–2 A current). - Insert the delivery tube under the soapy water. Hydrogen forms at the cathode, oxygen at the anode, in a 2:1 volume ratio. - Wait until air in the tubing has been displaced by the hydrogen–oxygen mixture. - Use a spatula or teaspoon on a long stick to collect bubbles from the surface. - Ignite the bubbles with a match on the end of a pole; they explode with a sharp crack. ====Links==== Exploding bubbles of hydrogen and oxygen - Royal Society of Chemistry: {{youtube>vcLHBS0yIVQ?}}\\ Hydrogen Bubbles - Exploding Bubbles - SpanglerScienceTV: {{youtube>zrg8XlHEDJ8?}}\\ 📄 Exploding bubbles of hydrogen and oxygen - RSC: [[https://sciencequiz.net/ichemistry/wp-content/uploads/2019/02/Experiment-71-Exploding-bubbles-of-hydrogen-and-oxygen.pdf]]\\ ====Variations==== * Use a Hoffman voltameter to collect and show the 2:1 gas ratio separately before igniting. * Use graphite rods as the electrodes. * Experiment with different voltages and concentration of sulfuric acid. * Compare loudness of bubbles filled with pure hydrogen, pure oxygen, and the hydrogen–oxygen mixture. ====Safety Precautions==== * Wear safety goggles and ear protection. * Perform only as a teacher demonstration — never scale up. * Keep the Bunsen burner at least 1 m from the electrolysis setup. * Lead foil is toxic — wash hands after handling and avoid ingestion. * Sulfuric acid is corrosive — avoid contact with skin and eyes. * Never ignite gas directly at the end of the tubing. * Ensure the room is ventilated and that students keep a safe distance from the bubbles - it can be very loud. ====Questions to Consider==== * Why is twice as much hydrogen produced as oxygen? (Because water has formula H2O, so electrolysis gives a 2:1 volume ratio of H2:O2.) * Why do the bubbles explode so violently compared with burning pure hydrogen? (Because the gases are mixed in the exact stoichiometric ratio, allowing all reactants to combust at once.) * Why is sulfuric acid added to the water for electrolysis? (It increases conductivity by providing ions.) * Why is this reaction considered both endothermic and exothermic? (Electrolysis requires energy to split water — endothermic; recombination releases energy explosively — exothermic.) * How could hydrogen fuel be produced for large-scale energy use? (By water splitting, though efficient catalysts and energy sources are still being researched.)