======Flame Tests====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Flame Test Colors ====Summary==== {{$demo.summary}} ====Procedure==== - Label small beakers for each metal salt and prepare about 50 mL of ≈1.0 M aqueous solutions for BaCl2, CaCl2, CuCl2, LiCl, KCl, NaCl, and SrCl2. - Soak separate wooden splints in each solution overnight; reserve a water beaker to quench used splints. - Set up a Bunsen burner in a clear area and light it with a striker; dim room lights if possible. - One at a time, pass a soaked splint slowly through the hottest part of the flame and observe the color; place the used splint in the water beaker. - Record the observed color and estimate wavelength or frequency using a visible spectrum chart. - For a mixture test, place a copper and a strontium splint in the flame together and identify both colors present. - If desired, present two unknown splints for students to identify from their color matches. ====Links==== Flame Test Colors - Step by Step Science: {{youtube>TMz_XR3o5mg?}}\\ The Flame Test Experiment- The Chemistry of Colorful Flames - Chem Camp with Mrs. Newman: {{youtube>7hC-KyFraCQ?}}\\ 📄 The Flame Test - ACS Institute: [[https://institute.acs.org/acs-center/lab-safety/education-training/safer-experiments/flame-test.html]]\\ ====Variations==== * Look at through a spectroscope to filter the individual color bands. * Spray the solutions onto a flame using a perfume sprayer. ====Safety Precautions==== * Wear safety goggles, lab coat or apron, and tie back hair. * Use only aqueous salt solutions on splints; do not use flammable solvents such as methanol or ethanol. * Keep flammables away from the burner and maintain a clear workspace. * Some salts are highly toxic; refer to safety data sheets before use. * Quench used splints in water and dispose of residues sensibly. ====Questions to Consider==== * Which ions produced each flame color, and how can color be used to identify an unknown? * Using c = λν, convert an observed wavelength to frequency and vice versa; which colors correspond to higher energy photons? * How do electronic energy levels and electron transitions explain the observed discrete colors? * How is this safer method different from the traditional rainbow demo that used alcohol fuels on the bench?