======Endothermic and Exothermic Dissolving====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Hot and Cold Packs, Energy Changes When Substances Dissolve ====Summary==== {{$demo.summary}} ====Procedure==== - Put on safety goggles and gloves. - **Experiment 1 (Endothermic):** - Place a small amount of solid ammonium chloride and solid barium hydroxide in a beaker. - Stir the mixture with a glass rod. - Observe how the temperature drops sharply, and note that the beaker feels very cold (sometimes cold enough to freeze water underneath). - **Experiment 2 (Exothermic):** - Place a small piece of calcium carbonate (e.g., marble chip) into a beaker. - Add dilute sulfuric acid. - Observe the reaction: fizzing/bubbling due to carbon dioxide release, and the beaker becoming warm as heat is released. - Compare the temperature changes in both experiments. ====Links==== demonstration of exothermic and endothermic reactions - Mireille Tannous: {{youtube>NHOHKH3808c?}}\\ Hot Pack vs Cold Pack - Exothermic vs Endothermic Chemical Reactions - Ed Reeves: {{youtube>u8ZmX9tJ3v8?}}\\ 📄 Temperature Changes in Dissolving - ACS: [[https://www.acs.org/middleschoolchemistry/lessonplans/chapter5/lesson9.html]]\\ ====Variations==== * Try other common exothermic reactions, such as dissolving calcium chloride in water. * Try other endothermic reactions, such as dissolving potassium chloride or ammonium nitrate in water. * Use a thermometer to measure exact temperature changes for quantitative comparison. ====Safety Precautions==== * Always wear safety goggles and gloves. * Handle sulfuric acid carefully—use only dilute solutions. * Barium hydroxide is corrosive and toxic; avoid skin contact and inhalation. * Conduct the experiments in a well-ventilated area or under a fume hood. * Dispose of chemical waste according to school or local regulations. ====Questions to Consider==== * Which reaction was exothermic and which was endothermic? (Calcium carbonate + sulfuric acid is exothermic; barium hydroxide + ammonium chloride is endothermic.) * Why does the temperature decrease in an endothermic reaction? (The reaction absorbs energy from the surroundings, lowering the temperature.) * Why does the temperature increase in an exothermic reaction? (The reaction releases energy to the surroundings as heat.) * What observable evidence helps distinguish these two types of reactions? (Temperature change, container hot or cold, gas release, and other visual signs.) * How do these energy changes connect to real-life examples like cold packs and hand warmers? (Cold packs use endothermic dissolving reactions; hand warmers use exothermic crystallization or oxidation reactions.)