======Electrolysis of Water====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Splitting Water with Electricity ====Summary==== {{$demo.summary}} ====Procedure==== - Fill the electrolysis apparatus with dilute sodium sulfate or sulfuric acid solution , ensuring both compartments are filled completely, then close the stopcocks. - Connect the apparatus to a direct current power supply set to about 10–12 volts. - Allow electrolysis to occur, collecting hydrogen gas at the cathode and oxygen gas at the anode. - Test the hydrogen by igniting it with a lit splint or bunsen burner. - Test the oxygen by inserting a glowing splint into the collected gas; it will reignite or glow more brightly. - Rinse the apparatus thoroughly after the demonstration to prevent corrosion of electrodes. ====Links==== Science at Home - SE1 - EP1: Electrolysis of Water - The Sci Guys (a much simpler setup): {{youtube>T-OwWOYHhMI?}}\\ Electrolysis of Water - Scott Milam: {{youtube>vFR9zUGt2C4?}}\\ 📄 Electrolysis of Water - University of Washington: [[https://chem.washington.edu/lecture-demos/electrolysis-water]]\\ ====Variations==== * Add phenolphthalein indicator to the solution to show hydroxide ion formation at the cathode (solution turns pink). * Collect larger amounts of hydrogen and oxygen to combine in a test tube for a small “pop” explosion. ====Safety Precautions==== * Safety goggles required. * Keep hydrogen away from open flames until intentionally tested. * Do not exceed 12 volts to avoid damaging equipment or blowing fuses. * Handle glassware and test tubes carefully to avoid breakage. * Rinse apparatus immediately after use to prevent electrode corrosion. ====Questions to Consider==== * What are the products formed when water undergoes electrolysis? (Hydrogen and oxygen gases.) * Why is sodium sulfate added to the water? (It increases conductivity by providing ions but does not take part in the reaction.) * How can you identify oxygen gas in this experiment? (It relights a glowing splint.) * Why does hydrogen make a “pop” sound when ignited? (Because hydrogen combusts rapidly with oxygen to form water.) * How does this experiment demonstrate conservation of matter? (The atoms of hydrogen and oxygen in water are rearranged into new molecules without being lost.)