======Carbon Dioxide Equilibrium in Water====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Effect of Pressure on Carbon Dioxide Solubility ====Summary==== {{$demo.summary}} ====Procedure==== -Draw carbonated water into a large syringe and add a few drops of bromcresol green indicator. -Seal the syringe tightly with a cap to trap the liquid and gas. -Observe the initial color of the solution; under pressure, CO2 remains dissolved and the solution is more acidic. -Gently pull back on the plunger to reduce pressure inside the syringe. -Watch for bubble formation as CO2 comes out of solution and note the color change of the indicator as the acidity decreases. -Push the plunger back in to increase pressure again; observe that some CO2 redissolves, shifting the indicator color back toward acidic. ====Links==== Le Chatelier and Pressure Changes using carbonated water - Linda Hanson: {{youtube>1GwpZuBJOYQ?}}\\ LeChatelier's Principle and the Solubility of Carbon Dioxide - FlinnScientific: {{youtube>QtCRxvCxa6M?}}\\ ====Variations==== *Repeat with different indicators (e.g., universal indicator or phenol red) to compare color ranges. *Try using sparkling water at different temperatures; colder samples retain more CO2 and show slower color change. ====Safety Precautions==== *Do not pull the plunger out completely; carbonated liquid may spray. *Keep the syringe upright to minimize spillage during pressure changes. *Wear safety glasses and protect work surfaces from staining by the indicator. ====Questions to Consider==== *Why does the indicator show a color change when the syringe pressure is lowered? (Less CO2 dissolves, lowering H+ concentration and increasing pH.) *How does Henry’s Law explain the behavior of CO2 in the syringe? (Gas solubility is proportional to its partial pressure above the liquid.) *Why does the solution become acidic when CO2 is dissolved? (CO2 reacts with water to form carbonic acid, releasing H+ ions.) *What differences would you expect if you repeated the demonstration with warm carbonated water? (Less CO2 would dissolve, so the solution would be less acidic and lose its fizz faster.)