/*******************************************************************************************************/ /* TITLE - Required */ /*******************************************************************************************************/ ======Cannon Fire Reaction====== /*******************************************************************************************************/ /* GREY BOX INFORMATION - Required */ /*******************************************************************************************************/ /* Leave this unchanged */ **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ /*******************************************************************************************************/ /* Alternative Titles - Optional (But the text must be left in) */ /*******************************************************************************************************/ **Alternative titles:** Cannon Fire /*******************************************************************************************************/ /* SUMMARY - Required */ /*******************************************************************************************************/ /* Leave this unchanged */ ====Summary==== {{$demo.summary}} /*******************************************************************************************************/ /* PROCEDURE - Optional */ /*******************************************************************************************************/ ====Procedure==== - Place a heat mat on the bench and set up a tripod and safety screen facing the audience. - In a large porcelain evaporating basin, measure about 30 mL of 20 volume (6%) hydrogen peroxide. - Add about 20 mL of ethanol to the same basin and swirl gently to mix. - Stir in a small spatula measure of a flame-coloring salt (for example, lithium chloride for red). - Move the basin onto the tripod where it is stable and clearly visible behind the safety screen. - Ignite the mixture at arm’s length using a tapered spill or extended lighter. - Using a spatula, sprinkle small portions of solid potassium permanganate onto the burning liquid over time; pause between additions to let each portion react. - Continue adding tiny amounts until a series of sharp cracks and bangs is produced; do not add too quickly. - Extinguish any residual flame safely and allow the apparatus to cool before disposal and cleanup. /*******************************************************************************************************/ /* Links - Optional */ /*******************************************************************************************************/ ====Links==== Cannon Fire - Any Excuse for a Chemistry Experiment: {{youtube>R6MHVXxeK3M?}} \\ 📄 Full procedure and risk assessment - SSERC: [[https://www.sserc.org.uk/resources/chemistry-resources/chemistry-resource-list/cannon-fire/]] /*******************************************************************************************************/ /* VARIATIONS - Optional */ /*******************************************************************************************************/ ====Variations==== * Try different metal salts to compare flame colors (e.g., sodium chloride for yellow, copper(ii) chloride for green-blue), ensuring the salt is dry and used sparingly. * Dim the room lights so the flame color is more visible, keeping the safety screen in place. /*******************************************************************************************************/ /* SAFETY PRECAUTIONS - Required */ /*******************************************************************************************************/ ====Safety Precautions==== * Safety glasses or goggles required; wear a lab coat and heat-resistant gloves. * Use a safety screen between the apparatus and observers at all times. * Hydrogen peroxide (20-volume) is corrosive/harmful; avoid skin and eye contact and clean spills immediately. * Ethanol is highly flammable; keep sources of ignition away and cap bottles promptly. * Add potassium permanganate only in tiny portions; never dump in all at once to avoid violent spattering or ejection of burning liquid. * Perform on a heat mat with a stable tripod; keep combustible materials clear of the setup. * Handle hot ceramics with tongs and allow full cooling before touching or moving. * Ensure good ventilation; have a fire blanket and suitable extinguisher nearby. * Dispose of cooled residues according to local guidance for oxidizers and flammable waste. /*******************************************************************************************************/ /* QUESTIONS TO CONSIDER - Optional */ /*******************************************************************************************************/ ====Questions to Consider==== * What evidence shows a chemical reaction is occurring? (light, heat, sound, gas evolution, and color changes) * Identify the oxidizers and reducer in the reaction. (hydrogen peroxide and potassium permanganate are the oxidizers, ethanol is the reducer) * How does adding a salt change the flame appearance? (metal ions emit characteristic colors when excited in the flame; e.g., Li+ gives red) /*******************************************************************************************************/ /* DEMONSTRATION INFORMATION - Required */ /*******************************************************************************************************/ /* Complete information in the Demonstration Info box below, following instructions exactly. */