======Molecular Mass of Butane====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Molar Mass of Butane by Gas Collection ====Summary==== {{$demo.summary}} ====Procedure==== - Fill a large container with water and invert a graduated cylinder full of water into it. Clamp the cylinder securely. - Weigh the cigarette lighter to obtain its initial mass. - Insert the lighter’s nozzle under the mouth of the inverted graduated cylinder and release butane gas so that it displaces the water, collecting a measurable volume of gas. - After collecting sufficient gas, remove the lighter and reweigh it to find the mass of butane released. - Record the volume of butane gas collected, the temperature of the water bath, and the atmospheric pressure. - Correct the collected gas volume for water vapor pressure. - Use the ideal gas law (PV = nRT) to calculate the moles of butane. - Determine the molar mass by dividing the mass of butane released by the calculated number of moles. ====Links==== Experiment 18 - The Molar Mass of Butane - Phil Reedy: {{youtube>JlxyfE6YnsU?}}\\ Determining the Molar Mass of Butane - Lab Hamster: {{youtube>OiQmzia0-Y8?}}\\ 📄 Molar Mass of Butane - Flinn Scientific: [[https://www.flinnsci.com/api/library/Download/a2be5b406f58415b80fbcc3c02c9d932?srsltid=AfmBOop_1ugq9j-kmdhQpOIqqcOoaF4pfJRkr1_Q2bIzTOPJdCVcmX2u]]\\ ====Variations==== * Repeat the experiment with different collected volumes to improve accuracy. * Collect gases from other small lighters or gas cartridges to compare calculated molar masses. ====Safety Precautions==== * Butane is highly flammable—keep flames and sparks away from the experiment. * Perform in a well-ventilated area to avoid buildup of butane vapors. * Wear safety goggles to protect from splashes or accidents. * Handle the lighter carefully; do not overheat or damage it. * Dispose of excess butane outdoors, not in a closed room. ====Questions to Consider==== * Why must the gas volume be corrected for water vapor pressure? (Because the collected gas is a mixture of butane and water vapor.) * How does temperature affect the calculated number of moles of gas? (Higher temperatures increase gas volume at constant pressure, leading to different mole calculations.) * What assumptions are made when using the ideal gas law? (That the gas behaves ideally, with negligible molecular volume and no intermolecular forces.) * How would experimental errors such as gas leaks or inaccurate weighing affect the calculated molar mass? (They would lead to incorrect mass or volume measurements, skewing the molar mass result.)