======Ammonia and Hydrogen Chloride Diffusion====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Comparing Gas Diffusion Rates ====Summary==== {{$demo.summary}} ====Procedure==== - Place a long glass tube horizontally on a retort stand and secure it with clamps. - Soak a small ball of cotton wool with aqueous ammonia and insert it a few centimeters into one end of the tube, sealing with a rubber bung. - Using rinsed tweezers, soak another cotton ball with concentrated hydrochloric acid and insert it into the opposite end of the tube, also sealing with a bung. - Leave the tube undisturbed and observe over 15–20 minutes. - Watch for the formation of a white ring of ammonium chloride where the two gases meet. Note its position relative to each end. ====Links==== Ammonia and hydrogen chloride diffusion experiment - Nigel Baldwin: {{youtube>OxhWwPMlgdA?}}\\ 📄 Diffusion of ammonia and hydrogen chloride gas - Institute of Physics: [[https://spark.iop.org/diffusion-ammonia-and-hydrogen-chloride-gas]]\\ ====Variations==== * Try using tubes of different lengths to see how the time for ring formation changes. * Instead of a tube, put ammonia and hydrochloric acid in two separate small beakers, then cover them with an inverted larger beaker. * Leave the experiment overnight in the fumehood. ====Safety Precautions==== * Wear safety goggles and a lab coat. * Conduct the experiment in a well-ventilated lab or outdoors, as both ammonia and HCl vapors are irritating and corrosive. * Handle concentrated hydrochloric acid and concentrated ammonia carefully; avoid skin and eye contact. * Dispose of cotton wool safely in a fume hood after use. * Rinse tweezers after handling each cotton wool sample to avoid corrosion or cross-contamination. ====Questions to Consider==== * Why does the white ring of ammonium chloride form closer to the hydrochloric acid end? (Because ammonia molecules, being lighter, diffuse faster than hydrogen chloride molecules.) * How does this experiment provide evidence for the particle model of gases? (The movement and eventual meeting of invisible particles is inferred from the appearance of the solid ring.) * Why do lighter molecules move faster at the same temperature? (Because the average kinetic energy is the same for all particles at a given temperature, so lighter particles must have higher speeds.) * What is the balanced equation for the reaction observed? (NH3(g) + HCl(g) → NH4Cl(s).)